Think of output 6 as a place holder.
Go to ports and pins> outputs scroll down and look for out put 6, enable it and assign it a port and pin and that should do it. Again i haven't used it yet so i am not the best to answer all these questions i am just guessing. So take everything i say with a grain of salt.

My diode driver can accept ttl, or analog. If your ps has a true + and - input (balanced) then you should be able to simply tie the minus to gnd and apply ttl to the + input. You may want to check your manual carefully, I would also recommend an opto isolated break out board in case the Chinese ps isn't up to snuff.
Chad