I'm using PoExtBusOC16CNC which have no IO periphery so I don't now where this pins could be used.
On the PoExtBusOC16CNC I have connected x,y,z leadshine stepper drivers.
On the pokeys are connected: 9,11,51- PoExtBusOC16CNC; 17- pwm output for VFD; 52- Emergency s.; 35- DO for start the spindle.
I can send a configuration if you are so friendly to check it.