The only way you can do it with Mach3 is IF you are only doing indexing the A axis then cut. You would apply a macro to unlock the brake , wait with dwell THEN move A. Same with stop Stop motion, call macro to apply brake, wait delay then continue.
Most of that would be controlled from the CAM post or hand coding.
G0 X10 Y10
M100 ( Release Brake, wait 1/2 sec)
A100
code
code
code
A360
M101 (Apply brake, wait 1/2 sec)
G0 X0Y0
etc
etc
(;-) TP