You can tell mach3 that the A axis is a rotary Axis and go to the MDI page, and type G0 or G1 A90 to get a 90 degrees of rotation
Menu - Config, General config, check A is angular.
I don't know what kind of an arc you are trying to machine.
If this is an ellipse, you'll have to draw it in a cam software in order to get the right displacement and that feed are synchronize with others Axis.