I would run your program at 50% feed and then at 25% feed rate and see if you get a nice corner, if you do then it must be flex in the machine. If it was overrun then the next move would be a straight line from the bottom of the gouge point.
Are you using solid carbide tools or carbide tipped tools, solid carbide are better less flex in the shank. Also keep the tools as short as possible.
It may be worth checking your CAM software some have an option to slow down in the corners to stop this type of problem also filleting the sharp corners with a small radius can also stop this.