If you have two points that you can measure accurately then you can quickly calc to find the angle and use a G68 or 69....
Can probably use CopyCat ( used with a video camera, CoptCat Manual fcan be found in in members docs ) to easily get two points and modify
the code on the fly for the G68. I never fooled with G68 or G69 in Mach.
There are some macros written so you can touch off the vise jaws and account for them not being perpendicaular to the axis.
A friend wrote his owne touchoff routines to accomplish what you want to do. I don't have them, frankly i don't use them or have any interest.
I still believe in spending a few minutes to square things up ............
Just a few comments in passing by,
RICH