You are very welcome.
Since I posted the info, I have discovered that although for me 90% of the time the second port (ribbon cable) was assigned LPT2, the physical ports on the card are not locked in any order and either can be assigned LPT2 or LPT3.
To get the addresses, follow this sequece:
Start>Control Panel>System>Hardware>Device Manager>Ports>Printer Port>Resources
What you seek is the first hex address given for LPT2 and for LPT3. For the port physically on the card, give Mach3 the address shown for LPT3 (that's USUALLY what it is). If that does not work, then just try the address for LPT2 and it should spring to life.
I did some testing of my own as soon as I installed the card to figure out which port was which. Like you said, it assigned LPT2 to the ribbon cable and LPT3 to the card. Before realizing I could swap them around via Windows Config, I physically moved them in my computer case so that there were in order from top to bottom
I wish I would have seen this thread a few days ago...I just ordered this card. http://www.tigerdirect.com/applications/SearchTools/item-details.asp?Sku=C250-3706
Crossing my fingers it will work
It may, but keep us informed. We could make this thread into a "various PCI parallel ports that play nice with Mach3" thread.